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Formation of an Iron(II) Carbene–Thiolato Complex by Insertion of Carbon Monoxide into an SiC Bond

✍ Scribed by Masahiro Yuki; Tsukasa Matsuo; Hiroyuki Kawaguchi


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
140 KB
Volume
116
Category
Article
ISSN
0044-8249

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CCα Insertion: Insertion of an Alkyne in
✍ Seda Ünaldi; Rudolf Aumann; Roland Fröhlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of