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Synthesis of (1-alkynyl)dicarbonylcyclopentadienyliron complexes by palladium-catalyzed Sonogashira-type carbon–iron bond formation

✍ Scribed by Ryotaro Nakaya; Shigeo Yasuda; Hideki Yorimitsu; Koichiro Oshima

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
533 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of [CpFe(CO) 2 I] with terminal alkynes in the presence of catalytic amounts of dichlorobis(triphenylphosphine)palladium and copper iodide in aliphatic amine/THF results in Sonogashira-type carbon-iron bond formation to yield [CpFe(CO) 2 (C"CR)] in good yields.

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