Iron catalyzed synthesis of hollow carbon nanocapsules by resistive heating
β Scribed by Kizuka, Tokushi; Fujii, Jun; Miyazawa, Kun'ich
- Book ID
- 122951454
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 598 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0925-9635
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Treatment of [CpFe(CO) 2 I] with terminal alkynes in the presence of catalytic amounts of dichlorobis(triphenylphosphine)palladium and copper iodide in aliphatic amine/THF results in Sonogashira-type carbon-iron bond formation to yield [CpFe(CO) 2 (C"CR)] in good yields.