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Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron–Corrole Complexes: Synthesis of a Crystalline Copolymer

✍ Scribed by Nakano, Koji; Kobayashi, Kazuki; Ohkawara, Takahiro; Imoto, Hideyuki; Nozaki, Kyoko

Book ID
120432029
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
306 KB
Volume
135
Category
Article
ISSN
0002-7863

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Synthesis of Heterobimetallic RuMn Compl
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## Abstract The heterobimetallic complexes [(η^5^‐C~5~H~5~)Ru(CO)(μ‐dppm)Mn(CO)~4~] and [(η^5^‐C~5~Me~5~)Ru(μ‐dppm)(μ‐CO)~2~Mn(CO)~3~] (dppm= bis‐diphenylphosphinomethane) have been prepared by reacting the hydridic complexes [(η^5^‐C~5~H~5~)Ru(dppm)H] and [(η^5^‐C~5~Me~5~)Ru(dppm)H], respectively,