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Coupling of Epoxides with Carbon Dioxide Catalyzed by Ruthenium Porphyrin Complex

✍ Scribed by Lili JIN; Tao CHANG; Huanwang JING

Publisher
Elsevier Science
Year
2007
Weight
252 KB
Volume
28
Category
Article
ISSN
1872-2067

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Synthesis of Heterobimetallic RuMn Compl
Synthesis of Heterobimetallic RuMn Complexes and the Coupling Reactions of Epoxides with Carbon Dioxide Catalyzed by these Complexes
✍ Man Lok Man; King Chung Lam; Wing Nga Sit; Siu Man Ng; Zhongyuan Zhou; Zhenyang πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 385 KB πŸ‘ 2 views

## Abstract The heterobimetallic complexes [(Ξ·^5^‐C~5~H~5~)Ru(CO)(μ‐dppm)Mn(CO)~4~] and [(Ξ·^5^‐C~5~Me~5~)Ru(μ‐dppm)(μ‐CO)~2~Mn(CO)~3~] (dppm= bis‐diphenylphosphinomethane) have been prepared by reacting the hydridic complexes [(Ξ·^5^‐C~5~H~5~)Ru(dppm)H] and [(Ξ·^5^‐C~5~Me~5~)Ru(dppm)H], respectively,