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Carbon dioxide hydrogenation catalyzed by ruthenium complexes immobilized on MCM-41

✍ Scribed by YU Ying-min; FEI Jin-hua; ZHANG Yi-ping; ZHENG Xiao-ming

Publisher
Elsevier
Year
2006
Tongue
Chinese
Weight
350 KB
Volume
34
Category
Article
ISSN
1872-5813

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## Abstract The water‐soluble ruthenium(II) complexes [Cp′RuX(PTA)~2~]Y and [CpRuCl(PPh~3~)(mPTA)]OTf (Cp′ = Cp, Cp\*, X = Cl and Y = nil; or X = MeCN and Y = PF~6~; PTA = 1,3,5‐triaza‐7‐phosphaadamantane; mPTA = 1‐methyl‐1,3,5‐triaza‐7‐phosphaadamantane) were used as catalyst precursors for the hy