Iron-Catalyzed Sonogashira Reactions
✍ Scribed by Mónica Carril; Arkaitz Correa; Carsten Bolm
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 305 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A small quantity of iron(II) triflate (2.5 to 5 mol%) catalyzes the aziridination reactions of enol silyl ethers with tosylimino(iodo)benzene (PhINTs) in acetonitrile to give α‐__N__‐tosylamido ketones by subsequent aziridine ring opening. Olefins are converted into aziridines by 5 mol%
## Abstract Iron‐catalyzed hydrosilylation is one of the most popular reduction reactions owing to the high natural abundance, low cost and low toxicity of iron and silicon. This paper introduces an advance in iron‐catalyzed hydrosilylation of olefins, aldehydes, ketones and amides. Some reactions