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Iron-catalyzed hydrosilylation reactions

✍ Scribed by Ming Zhang; Aiqin Zhang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
157 KB
Volume
24
Category
Article
ISSN
0268-2605

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✦ Synopsis


Abstract

Iron‐catalyzed hydrosilylation is one of the most popular reduction reactions owing to the high natural abundance, low cost and low toxicity of iron and silicon. This paper introduces an advance in iron‐catalyzed hydrosilylation of olefins, aldehydes, ketones and amides. Some reactions exhibit good functional group tolerance and chemoselectivities. These protocols provide economical, sustainable and practical tools for organic chemists. Copyright Β© 2010 John Wiley & Sons, Ltd.


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