Iron-Catalyzed Reactions in Organic Synthesis
β Scribed by Carsten Bolm; Julien Legros; Jacques Le Paih; Lorenzo Zani
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A small quantity of iron(II) triflate (2.5 to 5 mol%) catalyzes the aziridination reactions of enol silyl ethers with tosylimino(iodo)benzene (PhINTs) in acetonitrile to give Ξ±β__N__βtosylamido ketones by subsequent aziridine ring opening. Olefins are converted into aziridines by 5 mol%
## Abstract Ironβcatalyzed hydrosilylation is one of the most popular reduction reactions owing to the high natural abundance, low cost and low toxicity of iron and silicon. This paper introduces an advance in ironβcatalyzed hydrosilylation of olefins, aldehydes, ketones and amides. Some reactions