Iron-Catalyzed Arylmagnesiation of Aryl(alkyl)acetylenes in the Presence of an N-Heterocyclic Carbene Ligand.
β Scribed by Takafumi Yamagami; Ryo Shintani; Eiji Shirakawa; Tamio Hayashi
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 38 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract It was found that a nucleophilic __N__βheterocyclic carbene could be utilized as a ligand for Pd(0)βcatalyzed bismetallative cyclization of enynes in the presence of Bu~3~SnSiMe~3~. An imidazolium salt having a bulky alkyl group attached to both nitrogen atoms of its imidazolβ2βylidene
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