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Pd(0)-Catalyzed Bismetallative Cyclization of Enynes in the Presence of Bu3SnSiMe3 Using N-Heterocyclic Carbene as a Ligand.

✍ Scribed by Yoshihiro Sato; Noriko Imakuni; Miwako Mori

Publisher: John Wiley and Sons
Year: 2003
Weight: 212 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200329139

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Pd(0)-Catalyzed Bismetallative Cyclization of Enynes in the Presence of Bu3SnSiMe3 Using N-Heterocyclic Carbene as a Ligand

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## Abstract It was found that a nucleophilic __N__‐heterocyclic carbene could be utilized as a ligand for Pd(0)‐catalyzed bismetallative cyclization of enynes in the presence of Bu~3~SnSiMe~3~. An imidazolium salt having a bulky alkyl group attached to both nitrogen atoms of its imidazol‐2‐ylidene

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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