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Iron and Cobalt Ethylene Polymerization Catalysts Bearing 2,6-Bis(Imino)Pyridyl Ligands: Synthesis, Structures, and Polymerization Studies

✍ Scribed by Britovsek, George J. P.; Bruce, Michael; Gibson, Vernon C.; Kimberley, Brian S.; Maddox, Peter J.; Mastroianni, Sergio; McTavish, Stuart J.; Redshaw, Carl; Solan, Gregory A.; Strömberg, Staffan; White, Andrew J. P.; Williams, David J.

Book ID
121194197
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
244 KB
Volume
121
Category
Article
ISSN
0002-7863

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Iron(II)–ethylene polymerization catalys
Iron(II)–ethylene polymerization catalysts bearing 2,6-bis(imino)pyrazine ligands: Part I. Synthesis and characterization
✍ L. Beaufort; F. Benvenuti; A.F. Noels 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 247 KB

The synthesis of a new series of 2,6-bis(imino)pyrazinyl ligands, [Ar N C Pyz C N Ar] where the aryl groups Ar = naphtyl, 2,6dimethylphenyl, 2,6-diisopropylphenyl, 2,4,6-trimethylphenyl, and their iron(II) complexes is described starting from monoacetylpyrazine.