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Iron(II)–ethylene polymerization catalysts bearing 2,6-bis(imino)pyrazine ligands: Part II. Catalytic behaviour, homogeneous and heterogeneous insights

✍ Scribed by L. Beaufort; F. Benvenuti; A.F. Noels

Book ID: 108212766
Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 296 KB
Volume: 260
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2006.07.010

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Iron(II)–ethylene polymerization catalys

Iron(II)–ethylene polymerization catalysts bearing 2,6-bis(imino)pyrazine ligands: Part I. Synthesis and characterization

✍ L. Beaufort; F. Benvenuti; A.F. Noels 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 247 KB

The synthesis of a new series of 2,6-bis(imino)pyrazinyl ligands, [Ar N C Pyz C N Ar] where the aryl groups Ar = naphtyl, 2,6dimethylphenyl, 2,6-diisopropylphenyl, 2,4,6-trimethylphenyl, and their iron(II) complexes is described starting from monoacetylpyrazine.