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Preparation of Silica-Supported Bis(imino)pyridyl Iron(II) and Cobalt(II) Catalysts for Ethylene Polymerization

✍ Scribed by Kim, Il; Han, Byeong Heui; Ha, Chang-Sik; Kim, Jae-Kon; Suh, Hongsuk

Book ID
125951704
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
48 KB
Volume
36
Category
Article
ISSN
0024-9297

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The immobilization of the soluble precatalysts [(ArN C(Me)) 2 C 5 H 3 N]FeCl 2 , where Ar = 2,4,6-trimethylphenyl (A) or 2,6diisopropylphenyl (B), on supports derived from a spherical MgCl 2 -alcohol adduct yields active supported systems for ethylene polymerization. The activity of the supported ca

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## Abstract Summary: The number of active centers (__C__~P~) and propagation rate constants (__k__~P~) for polymerization of ethylene with supported catalysts LFeCl~2~/SiO~2~, LFeCl~2~/Al~2~O~3~ and LFeCl~2~/MgCl~2~ (L = 2,6‐(2,6‐(Me)~2~C~6~H~3~Nο£ΎCMe)~2~C~5~H~3~N), activated by an Al(__i__‐Bu)~3~ c