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Iridium(III) hydride complexes for the catalytic enantioselective hydrogenation of imines

✍ Scribed by Ng Cheong Chan, Y.; Osborn, J. A.

Book ID
115502678
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
286 KB
Volume
112
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Asymmetric hydrogenation of imines catal
Asymmetric hydrogenation of imines catalysed by carboxylato(diphosphine)iridium(III) complexes
✍ RafaΓ«l Sablong; John A Osborn πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 234 KB

The synthesis of three new families of monomeric carboxylato(diphosphine)iridium(Ill) complexes is described (e.g. diphosphine = diop, binap, bdpp). Some of these complexes catalyse the asymmetric hydrogenation of prochiral imines to amines in good activity and enantioselectivity.