Asymmetric Hydrogenation of Imines and O
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Anna Trifonova; Jarle S. Diesen; Pher G. Andersson
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Article
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2006
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John Wiley and Sons
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English
β 254 KB
π 1 views
## Abstract Herein we describe the synthesis of a new class of chiral phosphineβoxazolines and their application as ligands in iridiumβcatalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize