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Iridium-HetPHOX Complexes for the Catalytic Asymmetric Hydrogenation of Olefins and Imines.

✍ Scribed by Pier Giorgio Cozzi; Frederik Menges; Stefan Kaiser


Publisher
John Wiley and Sons
Year
2003
Weight
92 KB
Volume
34
Category
Article
ISSN
0931-7597

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Asymmetric Hydrogenation of Imines and O
✍ Anna Trifonova; Jarle S. Diesen; Pher G. Andersson πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 254 KB πŸ‘ 1 views

## Abstract Herein we describe the synthesis of a new class of chiral phosphine‐oxazolines and their application as ligands in iridium‐catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize