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Asymmetric Hydrogenation of Aromatic Olefins Catalyzed by Iridium Complexes of Proline-Derived Phosphine—Oxazoline Ligands.

✍ Scribed by Guopin Xu; Scott R. Gilbertson

Publisher
John Wiley and Sons
Year
2003
Weight
151 KB
Volume
34
Category
Article
ISSN
0931-7597

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Asymmetric Hydrogenation of Imines and Olefins Using Phosphine-Oxazoline Iridium Complexes as Catalysts
✍ Anna Trifonova; Jarle S. Diesen; Pher G. Andersson 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract Herein we describe the synthesis of a new class of chiral phosphine‐oxazolines and their application as ligands in iridium‐catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize