Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Phenols
✍ Scribed by Qing-Feng Wu; Wen-Bo Liu; Chun-Xiang Zhuo; Zi-Qiang Rong; Ke-Yin Ye; Prof. Dr. Shu-Li You
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 271 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0044-8249
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec
## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d