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Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Phenols

✍ Scribed by Qing-Feng Wu; Wen-Bo Liu; Chun-Xiang Zhuo; Zi-Qiang Rong; Ke-Yin Ye; Prof. Dr. Shu-Li You


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
271 KB
Volume
123
Category
Article
ISSN
0044-8249

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Iridium-Catalyzed Asymmetric Isomerizati
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 2 views

## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec

Iridium-Catalyzed Asymmetric Isomerizati
✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 373 KB 👁 2 views

## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d