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Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids

✍ Scribed by Yamashita, Yasuhiro; Gopalarathnam, Apsara; Hartwig, John F.

Book ID
120415340
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
32 KB
Volume
129
Category
Article
ISSN
0002-7863

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Iridium-Catalyzed Asymmetric Isomerizati
Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
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## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d

Iridium-Catalyzed Asymmetric Isomerizati
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✍ Luca Mantilli; David Gérard; Sonya Torche; Céline Besnard; Clément Mazet 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 2 views

## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec