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Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols

✍ Scribed by Ahlsten, Nanna; Bermejo Gómez, Antonio; Martín-Matute, Belén

Book ID
120451314
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
524 KB
Volume
52
Category
Article
ISSN
0044-8249

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Iridium-Catalyzed Asymmetric Isomerizati
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## Abstract **Unter sehr milden Reaktionsbedingungen** vermitteln Iridiumhydridkatalysatoren die Isomerisierung primärer Allylalkohole. Die besten Katalysatoren, darunter (__R__)‐**1**, liefern die gewünschten chiralen Aldehyde mit ausgezeichneten Enantioselektivitäten und in guten Ausbeuten. Auf d

Iridium-Catalyzed Asymmetric Isomerizati
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## Abstract **Nothing to sm(Ir)k at**: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (__R__)‐**1** (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselec