Transversely excited atmospheric (TEA) CO 2 laser-induced decomposition of divinylsilane in the gas phase yields unsaturated C 2 -C 4 hydrocarbons, benzene and vinylsilane, and it represents a convenient process for chemical vapour deposition of thin solid films composed of silicon carbide and polyc
IR laser-induced decomposition of dialkoxyalkanes
✍ Scribed by James E. Kuder; Douglas R. Holcomb
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 299 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Continuous -wave CO 2 -laser-induced gas-phase decomposition of H 3 SiOSiH 3 , dominated by elimination and polymerization of transient silanone H 2 Si=O and yielding silane and hydrogen as side-products, represents a convenient process for chemical vapour deposition of poly(hydridosiloxane) fi
The laser-induced decomposition of a solid azido polymer (GAP) is reported. A TEA CO 2 laser (tunable in the 920-1080 cm -1 range) is used and the dissociation yield is shown to correlate with the one photon absorption spectrum, although about 15 photons per molecule are required to break the weakes
## Abstract The multiple photon absorption and decomposition of ethanol irradiated by pulsed 9P18 infrared radiation (1048.7 cm^−1^) from a TEA CO~2~ laser has been studied in the fluence range 15 to 5 J cm^−2^. The absorption cross‐section is pressure‐dependent due to rapid collisional rotational