IR, EPR and optical absorption studies of some 2,2'-bipyridine complexes of Copper(II)
β Scribed by B. Balaiah; B.A. Sastry; M.N. Chary; G. Ponticelli; M. Massacesi
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 647 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0022-2860
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Copper(II) mononuclear complexes with the polyazamacrocyclic ligands NOTA (1,4,7-triazacyclononane-N,N',N''triacetate), DOTA (1,4,7,10-tetraazacyclo-dodecane-N,N',N'',N'''-tetraacetate), NOTP [1,4,7-triazacyclononane-N,N',N''-tris(methylenephosphonate)] and DOTP [1,4,7,10tetraazacyclododecane-N,N',N
Edge shifts (1E ), effective nuclear charge (Z eff ) and % covalency for some copper(II) mixed-ligand complexes were determined by investigating the copper K-absorption edge using a Seifert x-ray generator and a 0.4 m Cauchois-type bent crystal transmission spectrograph. The shift values are suggest