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Study of Copper(II) Polyazamacrocyclic Complexes by Electronic Absorption Spectrophotometry and EPR Spectroscopy

✍ Scribed by Carlos F. G. C. Geraldes; M. Paula M. Marques; Baltazar de Castro; Eulália Pereira

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 264 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(200003)2000:3<559::aid-ejic559>3.0.co;2-j

No coin nor oath required. For personal study only.

✦ Synopsis

Copper(II) mononuclear complexes with the polyazamacrocyclic ligands NOTA (1,4,7-triazacyclononane-N,N',N''triacetate), DOTA (1,4,7,10-tetraazacyclo-dodecane-N,N',N'',N'''-tetraacetate), NOTP [1,4,7-triazacyclononane-N,N',N''-tris(methylenephosphonate)] and DOTP [1,4,7,10tetraazacyclododecane-N,N',N'',N'''-tetrakis(methylenephosphonate)] were characterised in aqueous solution by electronic absorption spectrophotometry and electron paramagnetic resonance (EPR) spectroscopy. While two isomeric

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