The effects of conformation and coordina
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Mikio Yagi; Hayato Shirai; Jun Ohta; Jiro Higuchi
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Article
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1989
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Elsevier Science
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English
⚖ 328 KB
Time-resolved ESR spectra have been observed for the lowest triplet states of s-transd,b'dimethyl-2,2'-bipyridine (s-transdmbpy), metal-free s-cis-dmbpy and [Zn(dmbpy) I'+ in rigid solutions at 77 K. The results indicate that, following the conformational change of dmbpy, the sublevel initially popu