Ir-Catalyzed Asymmetric Hydrogenation: Ligands, Substrates and Mechanism
✍ Scribed by Klas Kaellstroem; Ian Munslow; Pher G. Andersson
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Although a lot of progress has been made in Rh-or Rucatalyzed asymmetric hydrogenation, Ir-catalyzed asymmetric hydrogenation is relatively unexplored. [1] Pfaltz and coworkers first reported several Ir-phosphinooxazoline complexes as catalysts for asymmetric hydrogenation. With leading efforts by P
Although a lot of progress has been made in Rh-or Rucatalyzed asymmetric hydrogenation, Ir-catalyzed asymmetric hydrogenation is relatively unexplored. [1] Pfaltz and coworkers first reported several Ir-phosphinooxazoline complexes as catalysts for asymmetric hydrogenation. With leading efforts by P
## Abstract A library of readily available phosphite–oxazole/thiazole ligands (**L1 a**–**g**–**L7 a**–**g**) was applied in the Ir‐catalyzed asymmetric hydrogenation of several largely unfunctionalized __E__‐ and __Z__‐trisubstituted and 1,1‐disubstituted terminal alkenes. The ability of the catal