Ir-Catalysed Asymmetric Hydrogenation: Ligands, Substrates and Mechanism
✍ Scribed by Klas Källström; Ian Munslow; Pher G. Andersson
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 589 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
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## Abstract A family of monodentate polystyrene‐supported phosphites, phosphoramidites and phosphanes has been prepared and evaluated as ligands in rhodium‐catalysed asymmetric hydrogenation and palladium‐catalysed asymmetric allylic alkylation. The supported ligands yielded active and enantioselec
## Abstract For Abstract see ChemInform Abstract in Full Text.
Although a lot of progress has been made in Rh-or Rucatalyzed asymmetric hydrogenation, Ir-catalyzed asymmetric hydrogenation is relatively unexplored. [1] Pfaltz and coworkers first reported several Ir-phosphinooxazoline complexes as catalysts for asymmetric hydrogenation. With leading efforts by P
Although a lot of progress has been made in Rh-or Rucatalyzed asymmetric hydrogenation, Ir-catalyzed asymmetric hydrogenation is relatively unexplored. [1] Pfaltz and coworkers first reported several Ir-phosphinooxazoline complexes as catalysts for asymmetric hydrogenation. With leading efforts by P