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New P,N-Ferrocenyl Ligands for the Asymmetric Ir-Catalyzed Hydrogenation of Imines.

โœ Scribed by Murthy N. Cheemala; Paul Knochel


Publisher
John Wiley and Sons
Year
2007
Weight
37 KB
Volume
38
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


New P,N Ligands for Asymmetric Ir-Cataly
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Scheme 1. The synthesis of 2-alkenylpyridines 13-15: a) [Pd(dba) 2 ] (2 mol %), dppf (2 mol %), alkenyl triflate 9 or 10, THF, LiCl, reflux, overnight; b) [Pd(PPh 3 ) 4 ] (5 mol %), PhB(OH) 2 , Na 2 CO 3 , toluene, MeOH, H 2 O, 85 8C, overnight. dba = dibenzylideneacetone, dppf = 1,1'-bis-(diphenylp

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