Ionic structure of solutions of alkali metals and molten salts
β Scribed by G. Chabrier; G. Senatore; M. P. Tosi
- Book ID
- 118292477
- Publisher
- Italian Physical Society
- Year
- 1982
- Tongue
- English
- Weight
- 679 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0392-6737
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π SIMILAR VOLUMES
We show that in contrast to MSA the HNC approximation can account qualitatively for the long wavelength scattering of metal-molten salt solutions. The difference is attributed to the defects of the MSA in the description of the short-range as well as the long-range order in the liquid.
The thermal emf of alkali metal-alkali halide mixtures is calculated on the basis of two models, the Pitzr model which suggests that the metal is completely dissociated to cation and electron, and the Rice model which assumes no dissociation. The Rice model gives surprisingly good agreement with the