Ion Association and Hydration in Aqueous Solutions of Nickel(II) and Cobalt(II) Sulfate
β Scribed by Ting Chen; Glenn Hefter; Richard Buchner
- Publisher
- Springer US
- Year
- 2005
- Tongue
- English
- Weight
- 226 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
## Abstract The first row transition metal ions Mn^2+^, Co^2+^, and Ni^2+^ have been studied by classical umbrella sampling molecular dynamics simulations. The water exchange mechanisms, estimates of reaction rates, as well as structural changes during the activation process are discussed. Mn^2+^ w
The hydration of several iron(H) compounds has heen studied by the MGssbauer technique and the X-ray diffraction method. The similarity of the MGssbauer parameters (isomer shift, quadrupole splitting) of aqueous iron(I1) salt solutions suggested that Fe\*+ contrary to Fe 3+ in the above solutions is
The pressure-jump method has been used to determine the rate constants for the formation and dissociation of nickel(I1) and cobalt(I1) complexes with cinchomeronate in aqueous solution at zero ionic strength. The forward and reverse rate constants obtained are k, = 2.27 x lo6 M-' s-' and k, = 3.81 x