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Hydration of iron(II) ion in aqueous solutions

✍ Scribed by E. Kálmán; T. Radnai; G. Pálinkás; F. Hajdu; A. Vértes

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
435 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis

The hydration of several iron(H) compounds has heen studied by the MGssbauer technique and the X-ray diffraction method. The similarity of the MGssbauer parameters (isomer shift, quadrupole splitting) of aqueous iron(I1) salt solutions suggested that Fe*+ contrary to Fe 3+ in the above solutions is present mainly in the form of the hexaaquo complex. Based on the analysis of X-ray data, however, the existence of moderate Fe (H,O)sA complex formation in addition to the dominating hexaaquo complexes in chloride and sulfate solutions could not he excluded.

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