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Iodine-catalyzed aziridination of alkenes using Chloramine-T as a nitrogen source

โœ Scribed by Takeya Ando; Daisuke Kano; Satoshi Minakata; Ilhyong Ryu; Mitsuo Komatsu

Book ID
108379110
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
515 KB
Volume
54
Category
Article
ISSN
0040-4020

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Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source. -The mechanism of the aziridination is not clear, but the participation of a iodine-Chloramine-T complex and an iodonium cation intermediate are suggested. Comparative reactions with p-substituted styrenes show that

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

ChemInform Abstract: Nitrogen Atom Trans
ChemInform Abstract: Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source.
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Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source. -Readily available and inexpensive chloramine-T (II) is found to undergo a Cu(I)-catalyzed reaction with unfunctionalized alkenes in anhydrous acetonitrile providing N-tosyl aziridines in moderate yield. -