Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source. -The mechanism of the aziridination is not clear, but the participation of a iodine-Chloramine-T complex and an iodonium cation intermediate are suggested. Comparative reactions with p-substituted styrenes show that
โฆ LIBER โฆ
ChemInform Abstract: Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source.
โ Scribed by T. ANDO; S. MINAKATA; I. RYU; M. KOMATSU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source.
-Readily available and inexpensive chloramine-T (II) is found to undergo a Cu(I)-catalyzed reaction with unfunctionalized alkenes in anhydrous acetonitrile providing N-tosyl aziridines in moderate yield. -
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