๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

ChemInform Abstract: Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source.

โœ Scribed by T. ANDO; S. MINAKATA; I. RYU; M. KOMATSU


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

โœฆ Synopsis


Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source.

-Readily available and inexpensive chloramine-T (II) is found to undergo a Cu(I)-catalyzed reaction with unfunctionalized alkenes in anhydrous acetonitrile providing N-tosyl aziridines in moderate yield. -


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Iodine-Catalyzed Az
โœ T. ANDO; D. KANO; S. MINAKATA; I. RYU; M. KOMATSU ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source. -The mechanism of the aziridination is not clear, but the participation of a iodine-Chloramine-T complex and an iodonium cation intermediate are suggested. Comparative reactions with p-substituted styrenes show that