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ChemInform Abstract: Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source.

โœ Scribed by T. ANDO; D. KANO; S. MINAKATA; I. RYU; M. KOMATSU

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Iodine-Catalyzed Aziridination of Alkenes Using Chloramine-T as a Nitrogen Source.

-The mechanism of the aziridination is not clear, but the participation of a iodine-Chloramine-T complex and an iodonium cation intermediate are suggested. Comparative reactions with p-substituted styrenes show that electron-rich alkenes react faster than electron-poor ones. The reaction can also be conducted with Chloramine-T analogues but the corresponding aziridines are only obtained in moderate yields. -(ANDO, T.;

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