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Iodine: A versatile reagent in carbohydrate chemistry III. Efficient activation of glycosyl halides in combination with DDQ

✍ Scribed by K.P.Ravindranathan Kartha; Mahmoud Aloui; Robert A Field

Book ID
104255792
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
255 KB
Volume
37
Category
Article
ISSN
0040-4039

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✦ Synopsis

Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Iodine: A Versatile
ChemInform Abstract: Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ.
✍ K. P. R. KARTHA; M. ALOUI; R. A. FIELD πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ. -Iodine, alone or in combination with DDQ, efficiently activates glycosyl halides for the reaction with alcohols to yield 1,2-trans-glycosides. Even sub-stoichiometric qua