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ChemInform Abstract: Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 2. Efficient Chemospecific Activation of Thiomethylglycosides.

✍ Scribed by K. P. R. KARTHA; M. ALOUI; R. A. FIELD

Book ID
112039007
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Iodine: A Versatile
ChemInform Abstract: Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ.
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Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ. -Iodine, alone or in combination with DDQ, efficiently activates glycosyl halides for the reaction with alcohols to yield 1,2-trans-glycosides. Even sub-stoichiometric qua

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Iodine, either alone or in combination with DDQ, has been found to serve as a very efficient reagent for the conversion of 'disarmed' glycosyl halides into simple 1,2-trans-glycosides. This reagent system represents a practical alternative to traditional heavy metal promoters in glycoside synthesis.