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ChemInform Abstract: Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ.

✍ Scribed by K. P. R. KARTHA; M. ALOUI; R. A. FIELD

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199711202

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✦ Synopsis

Iodine: A Versatile Reagent in Carbohydrate Chemistry. Part 3. Efficient Activation of Glycosyl Halides in Combination with DDQ. -Iodine, alone or in combination with DDQ, efficiently activates glycosyl halides for the reaction with alcohols to yield 1,2-trans-glycosides. Even sub-stoichiometric quantities of both I2 and DDQ give rise to excellent results. -(KARTHA, K.

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