RM vs. Ho relationships of two homologous series of pyridyl alkyl ketones were determined for systems of the type organic solvent/aqueous hydrochloric acid. In accordance with theoretical anticipations, linear 22~ vs. Ho plots were obtained for Ho values in the range -I, +I, RM values for methylene
Investigations on the relationship between molecular structure and chromatographic parameters : VII. Partition of phenols in systems of the type cyclohexane + polar solvent—formamide
✍ Scribed by E. Soczewiński; M. Ciszewska
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 527 KB
- Volume
- 96
- Category
- Article
- ISSN
- 1873-3778
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## SUbIMARY The RM values of phenol and' Ig methylated phenols on thin layers of cellulose impregnated with formamide, N-methylformamide or N,N-dimethylformamide are shown to be linearly related to the log of the concentration of the amide in the slurrying medium used in the preparation of the lay
The & vs. composition relationships of several solutes containing two or three functional groups (hydroxyl, amino and nitro groups), chromatographed in the system chloroform f electron-donor solvent-water, were compared with analogous plots obtained using simpler systems: cyclohexane i-chloroform-wa
Ethyl, propyl and butyl homologues of phenol have been chromatographed on layers of cellulose impregnated with simple amides (formamide, N-methylformamide and N,N-dimethylforrnamide) using hexane as the mobile phase. The plots of RM value vs. the logarithm of the concentration of the amide in the sl