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Studies in the relationship between molecular structure and chromatographic behaviour : XV. The behaviour of methylated phenols on thin layers of cellulose impregnated with formamide and with N-methylated formamides

✍ Scribed by R.J.T. Graham; L.S. Bark; J. Daly

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 1024 KB
Volume: 33
Category: Article
ISSN: 1873-3778
DOI: 10.1016/s0021-9673(00)98626-6

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✦ Synopsis

SUbIMARY

The RM values of phenol and' Ig methylated phenols on thin layers of cellulose impregnated with formamide, N-methylformamide or N,N-dimethylformamide are shown to be linearly related to the log of the concentration of the amide in the slurrying medium used in the preparation of the layers. The deviations from, the RM theory occurring at low and high amide concentrations are explained.

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