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Investigations into the AIBN initiation steps in the free radical polymerisation of acrylonitrile by the aminoxyl trapping technique

โœ Scribed by W. Ken Busfield; Ian D. Jenkins; P. Le

Book ID
104718956
Publisher
Springer
Year
1996
Tongue
English
Weight
354 KB
Volume
36
Category
Article
ISSN
0170-0839

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Free radical initiation mechanisms in th
Free radical initiation mechanisms in the polymerisation of diethyl fumarate and diethyl maleate studied by the nitroxide trapping technique
โœ W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 580 KB

The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The