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ChemInform Abstract: Initiation Processes in Copolymerization Studied by the Nitroxide Radical-Trapping Technique: Ethyl Vinyl Ether and Acrylonitrile.

โœ Scribed by W. K. BUSFIELD; I. D. JENKINS; M. J. MONTEIRO


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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Free radical initiation mechanisms in th
โœ W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 580 KB

The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The