Free radical initiation mechanisms in th
โ
W. Ken Busfield; Ian D. Jenkins; Kirstin Heiland
๐
Article
๐
1994
๐
Elsevier Science
๐
English
โ 580 KB
The radical trapping technique employing the stable nitroxide 1 as a scavenger has been used to study the reaction of t-butoxyl radicals with diethyl fumarate and with diethyl maleate. The major pathway with both monomers is hydrogen abstraction from the ester alkyl groups by t-butoxyl radicals. The