𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Investigations in the field of radiation-induced solid state polymerization—XXI. The influence of the conditions of crystallization on the solid phase polymerization of binary eutectic systems

✍ Scribed by Gy. Hardy; G. Nagy; J. Varga; J. Juhos

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
718 KB
Volume
3
Category
Article
ISSN
0014-3057

No coin nor oath required. For personal study only.

✦ Synopsis

A study has been made of the phase diagrams of the systems (N-vinyl succinimide-endo methylene tetrahydro phthalic acid mono allyl ester), (succinimide-endo methylene tetrahydro phthalic acid mono allyl ester) and (acetanilide--endo methylene tetrahydro phthalic acid mono aUyl ester). It has been concluded that a quasi-eutectic range of co-crystallization can be observed, depending on the conditions of undercooling and those of nucleation. It has been shown, for the case of N-vinyl succinimide-endo methylene tertahydro phthalic acid mono allyl ester, that the rate of solid phase polymerization changes directly with the proportion of the eutectic. It has been ascertained that, in binary systems, the proportion of the eutectic structure and consequently the observed rate of polymerization are markedly influenced by the tendency of the system to undercooling and by the nucleation during the crystallization.

📜 SIMILAR VOLUMES

The influence of monomer purity and crys
The influence of monomer purity and crystal defects on the radiation-induced solid-state polymerization of maleimides
✍ V.S. Ivanov; L.A. Petrukhno; L.F. Musienko 📂 Article 📅 1970 🏛 Elsevier Science 🌐 English ⚖ 375 KB

AbstraetmRadiation-induced polymerization of N-phenylmaleimide (N-FMI) of various degrees of purity has been studied. The degree of monomer conversion increases with increase of purity for processes in the liquid phase. The situation is more complicated for the solid-phase where degree of purity and

Investigations in the field of radiation
Investigations in the field of radiation-induced solid-state polymerization—XVI. Copolymerization in the eutectics of pairs of monomers which do not polymerize in the solid state (maleic anhydride and endomethylene-tetrahydrophthalic monopropyl ester)
✍ Gy. Hardy; N. Fedorova; K. Nyitrai 📂 Article 📅 1966 🏛 Elsevier Science 🌐 English ⚖ 239 KB

The solid state copolymerization ofmaleic anhydride and endomethylene-tetrahydrophthalic monopropyl ester was studied in the eutectic and other mixtures. It was concluded that the copolymerization of the monomers, neither of which polymerizes alone in the solid state, is made possible by the increas

Examination of variables in the radiatio
Examination of variables in the radiation-induced solid-state polymerization of trioxane
✍ Nelson S. Marans; Forrest A. Wessells 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 835 KB

Additional studies have been conducted on the radiation-induced, Solid-state polymerization of trioxane. The out-of-source polymerization rate has been investigated as a function of radiation dose and of temperature and time of polymerization. The empirical relationship of log time a Y (where Y is t