Investigations in Heterocycles. XV. Methylphenidate: A Versatile Intermediate in the Synthesis of Bicyclic Heterocycles with a Bridgehead Nitrogen Atom
β Scribed by DeStevens, George; Bernier, Marcel
- Book ID
- 127032183
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 502 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0022-2623
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π SIMILAR VOLUMES
## Abstract Some bridgehead nitrogen compounds possessing the CH(Me)βbridgehead Nο£ΏC(O) system have been synthesised and their configurations assigned. The chemical shifts of the proton geminal to the methyl group provides evidence for the existence of a deformed chair conformation for the methyl su
## Abstract Solvent effects on the ^1^H NMR parameters of perhydroβoxazolo[3,4β__a__]pyridine, perhydropyrido[1,2β__c__]β[1,3]oxazine and perhydrothiazolo[3,4β__a__]pyridine derivatives are described. Particularly marked are changes in the protonβproton geminal coupling constants of the NCH~2~O and