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Proton magnetic resonance studies of compounds with bridgehead nitrogen atoms—XXIII: Deformation of the piperidine ring in some bicyclic compounds possessing a bridgehead amide nitrogen atom

✍ Scribed by R. Cahill; T. A. Crabb

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
377 KB
Volume
5
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Some bridgehead nitrogen compounds possessing the CH(Me)‐bridgehead NC(O) system have been synthesised and their configurations assigned. The chemical shifts of the proton geminal to the methyl group provides evidence for the existence of a deformed chair conformation for the methyl substituted ring.

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