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Proton magnetic resonance studies of compounds with bridgehead nitrogen atoms—XXIV: The stereochemistry of octahydroimidazo [1,5-a] pyridine and of some N-acetyloctahydroimidazo [1,5-a] pyridines

✍ Scribed by T. A. Crabb; P. J. Chivers; R. F. Newton

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
297 KB
Volume
5
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Octahydroimidazo[1,5‐a]pyridine is shown to preferentially adopt the trans‐fused ring conformation in solution at room temperature. The NMR spectra of the rotational isomers of some N‐acetyloctahydroimidazo[1,5‐a]pyridines and N‐acetyloctahydro‐1H‐pyrido[1,2‐c]pyrimidine are described, and the stereochemistry about the N‐acetyl bonds and the cis or trans nature of the ring fusion defined.

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