1997 structure structure (solids and liquids) D 2000 ## 14 -006 Synthesis, Crystal Structure, and IR Investigations of ((NH3)5V-O-V( NH3)5)I4•NH3 and ((NH3)5Ti-O-Ti(NH3)5)I4•NH3. -Single crystals of the novel title compounds are prepared by room-temp. reaction of VI2 or TiI3, resp., with liquid a
✦ LIBER ✦
Investigation of Ti1.5Al–NH3 and Ti2Al–NH3 systems
✍ Scribed by V.N. Fokin; E.E. Fokina; I.I. Korobov; B.P. Tarasov
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 146 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0360-3199
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✦ Synopsis
Phase transformations in systems Ti 1.5 AleNH 3 and Ti 2 AleNH 3 are investigated under ammonia pressure of 1.5 MPa within the temperature range of 100e500 C in the presence of NH 4 Cl as an activator. Hydronitriding of the alloys Ti 1.5 Al and Ti 2 Al performed at 400 C is accompanied by formation of superfine hydridonitride phases of the intermetallides TiAl and Ti 3 Al with the particle sizes less than 1 micron.
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