Investigation of the tautomerism of 3-amino-2-acetyl-2-cyclohexene-1-ones by the NMR method
✍ Scribed by V. S. Bogdanov; V. V. Negrebetskii; V. A. Korenevskii; A. M. Moiseenkov; F. A. Lakhvich; A. A. Akhrem
- Book ID
- 112421801
- Publisher
- Springer
- Year
- 1971
- Tongue
- English
- Weight
- 372 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1573-9171
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## Abstract Long‐range CH correlation and long‐range selective proton decoupling (LRSPD), together with other standard NMR techniques, led to the complete ^13^C and ^1^H NMR spectral assignments of 2‐acetyl‐1‐tetralone and demonstrated its existence in the __endo__‐enolic form.
## Abstract 5‐Substituted 1,3,4‐thiadiazol‐2(3__H__)‐ones were shown to exist almost exclusively in the oxo tautomeric form with the aid of proton‐coupled ^15^N‐NMR spectra using the corresponding 3‐methyl‐1,3,4‐thiadiazol‐2(3__H__)‐ones and 5‐substituted‐2‐methoxy‐1,3,4‐thiadiazoles as reference c