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The Tautomerism of 1,3,4-Thiadiazol-2 (3H)-ones. A 15N-NMR-Study

✍ Scribed by Hans Fritz; Haukur Kristinsson; Tammo Winkler

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
249 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

5‐Substituted 1,3,4‐thiadiazol‐2(3__H__)‐ones were shown to exist almost exclusively in the oxo tautomeric form with the aid of proton‐coupled ^15^N‐NMR spectra using the corresponding 3‐methyl‐1,3,4‐thiadiazol‐2(3__H__)‐ones and 5‐substituted‐2‐methoxy‐1,3,4‐thiadiazoles as reference compounds.

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