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The synthesis of 3-amino-2-acetylcyclopent-2-en-1-ones

โœ Scribed by A. A. Akhrem; A. M. Moiseenkov; L. A. Saburova; A. I. Poselenov


Book ID
112432632
Publisher
Springer
Year
1969
Tongue
English
Weight
40 KB
Volume
18
Category
Article
ISSN
1573-9171

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Diastereoselective organocuprate additio
โœ Michael E. Jung; Willard Lew ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 251 KB

Addition of lower or higher order cuprates to the enone homoketals 4a-d give the alkylated products with de's ranging from 12% to 34%. The efftcient production of optically active materials from prochiral precursors by asymmetric induction is one of the goals in synthetic organic chemistry today.1