Investigation of the Presence of OH Radicals in Electrolyzed NaCl Solution by Electron Spin Resonance Spectroscopy
โ Scribed by Stan, Silvia D.; Woods, James S.; Daeschel, Mark A.
- Book ID
- 126040993
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 98 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0021-8561
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๐ SIMILAR VOLUMES
## Abstract The rearrangement of the 2โmethylโ2โphenylpropyl (or neophyl) radical **1** to the 1โmethylโ1โbenzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of diโ__t__โbutylperoxide in __t__โbutylbenzene at 270โ360 K. The energy of activation of the rearrangement is deter
## Abstract It is shown how electron spin resonance spectroscopy with modulated radical initiation can be used to analyze by purely spectroscopic means the secondโorder termination kinetics of systems containing two different kinds of radicals. The technique is applied to species generated by photo