Investigation of the 3d Rydberg state of CS2 by multiphoton ionization
โ Scribed by Li Li; X.T. Wang; X.N. Li; X.B. Xie
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 399 KB
- Volume
- 202
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Two-and three-photon resonance-enhanced multiphoton ionization spectra of the 3d Rydberg states of CS2 in the 154-160 nm region are reported. Noting that the selection rules for multiphoton transitions are quite different from those of one-photon transitions, the electronic origin of the 3dA8 RydbergeX transition of CSr is redefined to 63323 cm-'. The associated vibrational frequencies of the ut, v2 and the 2v,, 2v2 modes and the separation of the H and Q components of the v1 vibration in this excited state are determined,
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